78500-54-6

Basic information

• Product Name: benzyl azacycloheptane-2-ylideneacetate
• Synonyms: benzyl azacycloheptane-2-ylideneacetate
• CAS NO: 78500-54-6
• Molecular Weight: 245.321
• Mol File: 78500-54-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: benzyl azacycloheptane-2-ylideneacetate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl azacycloheptane-2-ylideneacetate(78500-54-6)
• EPA Substance Registry System: benzyl azacycloheptane-2-ylideneacetate(78500-54-6)

Safety Data

• Hazardous Substances Data: 78500-54-6(Hazardous Substances Data)

Upstream product

• 3338-03-2 2-methyl-4,5,6,7-tetrahydro-3H-azepine 
• 501-53-1 benzyl chloroformate 
• 100-51-6 benzyl alcohol 
• 70912-54-8 5-azepan-2-ylidene-2,2-dimethyl-[1,3]dioxane-4,6-dione 

Relevant articles and documents

A versatile route to β-enamino esters by acylation of lithium enamines with diethyl carbonate or benzyl chloroformate

A versatile route to β-enamino esters 1, using accessible starting materials, was developed. Lithiated enamines are allowed to react with diethyl carbonate or benzyl chloroformate with the formation of the β-enamino esters 1a or 1b. The reaction is rather general from a wide array of ketimines and aldimines. Products included cyclic β-enamino esters 1aa-ac, very useful for the synthesis of natural products.