78502-13-3

Basic information

• Product Name: 2,3,11,12-Tetraphenyl-2,3,11,12-didehydro<18>krone-6
• Synonyms: 2,3,11,12-Tetraphenyl-2,3,11,12-didehydro<18>krone-6
• CAS NO: 78502-13-3
• Molecular Weight: 564.678
• Mol File: 78502-13-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,3,11,12-Tetraphenyl-2,3,11,12-didehydro<18>krone-6(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,11,12-Tetraphenyl-2,3,11,12-didehydro<18>krone-6(78502-13-3)
• EPA Substance Registry System: 2,3,11,12-Tetraphenyl-2,3,11,12-didehydro<18>krone-6(78502-13-3)

Safety Data

• Hazardous Substances Data: 78502-13-3(Hazardous Substances Data)

Upstream product

• 6315-52-2 1,2-bis-tosyloxyethane 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 7460-82-4 diethylene glycol ditosylate 
• 4721-02-2 (Z)-stilbenediol 

Downstream Products

• 120-55-8 diethyleneglycol dibenzoate 
• 86491-79-4 1,9,12,20-Tetraphenyl-2,5,8,10,11,13,16,19,21,22-decaoxa-tricyclo[18.2.0.0^9,12]docosane 
• 78502-14-4 C₃₆H₃₂O₆ 
• 78502-15-5 C₃₆H₃₄O₆ 
• 78502-16-6 C₃₆H₃₄O₆ 
• 83024-42-4 2,3,11,12-tetraphenyl-18-crown-6 
• 72690-79-0 cis-anti-cis-2,3,11,12-Tetraphenyl-1,4,7,10,13,16-hexaoxacyclooctadecan 
• 72638-74-5 cis-syn-cis-2,3,11,12-Tetraphenyl-1,4,7,10,13,16-hexaoxacyclooctadecan 
• 82982-17-0 2,3,11,12-tetracyclohexyl-18-crown-6 

Relevant articles and documents

Unsaturated Crown Ethers. 3. Syntheses of Stilbeno Crown Ethers

A series of 6-, 9-, and 15-membered monostilbeno crown ethers (3) and 18-, 24-, and 30-membered distilbeno crown ethers (4), some of which are new compounds, were synthesized in the base-induced reactions of benzoin (1) with oligoethylene glycol ditosylates (2a-d) in homogeneous and heterogeneous solutions.The template effect is shown to be effective in controlling product yields and 4/3 ratios.

UNSATURATED CROWN ETHERS: STILBENO-CROWN ETHERS

Stilbenocrown ethers 3a,c and 4a,b were synthesized in a cyclization reaction of benzoin with oligoethylene glycol ditosylates (2a-c) under a phase-transfer condition.Extractions of aqueous alkali picrates (Na+-Cs+) were examined with the distilbenocrown ethers 4a,b, the partially-hydrogenated tetraphenylcrown ethers 6a,b, and the fully-hydrogenated tetracyclohexylcrown ethers 7a,b.