785051-54-9Relevant articles and documents
Cyclic boron esterification: screening organic room temperature phosphorescent and mechanoluminescent materials
Zhang, Kai,Sun, Qikun,Tang, Liangliang,Wang, Yanhui,Fan, Xiaojing,Liu, Linxi,Xue, Shanfeng,Yang, Wenjun
, p. 8733 - 8737 (2018)
Aryl boronic acids are a broad class of organic intermediates. Here, we show that their cyclic-esterification with appropriate dihydric alcohols is a simple and effective approach for screening organic room-temperature phosphorescent (RTP) and mechanoluminescent (ML) materials. Non RTP and ML active 4-(carbazol-9-yl)phenylboronic acid can be made into long-lived RTP emitters with lifetimes of 264 and 430 ms and a bright ML dye with blue emission by cyclic-esterification with 1,3-propanediol, 2,2-dimethyl-1,3-propanediol, and glycol, respectively. Systematic single crystal analysis and quantum chemical calculations indicate that cyclic borates dominate the molecular packing structures and intermolecular interactions, which is responsible for the different optical properties.
Synthesis and properties of butterfly-shaped naphthalimide-based AIE-active fluorescent dyes
Wang, Haina,Yu, Tianzhi,Zhang, Hui,Zhao, Yuling,Zhou, Meng
, (2022/01/11)
Two novel butterfly-shaped naphthalimide derivatives, 1,3-bis((carbazole-9-yl)-4-benzene-4–1,8-naphthalimide-N-)2,4,6-trimethylbenzene (DNI-Cz) and 1,3-bis((4-triphenylamine)-4–1,8-naphthalimide-N-)2,4,6-trimethylbenzene (DNI-TPA), were designed and synth
Communication of Bichromophore Emission upon Aggregation – Aroyl-S,N-ketene Acetals as Multifunctional Sensor Merocyanines
Biesen, Lukas,May, Lars,Nirmalananthan-Budau, Nithiya,Hoffmann, Katrin,Resch-Genger, Ute,Müller, Thomas J. J.
, p. 13426 - 13434 (2021/08/06)
Aroyl-S,N-ketene acetal-based bichromophores can be readily synthesized in a consecutive three-component synthesis in good to excellent yields by condensation of aroyl chlorides and an N-(p-bromobenzyl) 2-methyl benzothiazolium salt followed by a Suzuki coupling, yielding a library of 31 bichromophoric fluorophores with substitution pattern-tunable emission properties. Varying both chromophores enables different communication pathways between the chromophores, exploiting aggregation-induced emission (AIE) and energy transfer (ET) properties, and thus, furnishing aggregation-based fluorescence switches. Possible applications range from fluorometric analysis of alcoholic beverages to pH sensors.
COMPOUND FOR ORGANIC OPTOELECTRONIC DEVICE, COMPOSITION FOR ORGANIC OPTOELECTRONIC DEVICE, ORGANIC OPTOELECTRONIC DEVICE, AND DISPLAY DEVICE
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, (2021/09/03)
The present invention relates to a compound for an organic optoelectronic device, represented by Chemical Formula 1; a composition for an organic optoelectronic device, including same; an organic optoelectronic device; and a display device. The description of Chemical Formula 1 is the same as that defined in the specification.