78526-47-3

Basic information

• Product Name: 4-(cyclohexylthio)pyridine
• Synonyms: 4-(cyclohexylthio)pyridine
• CAS NO: 78526-47-3
• Molecular Weight: 193.313
• Mol File: 78526-47-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-(cyclohexylthio)pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(cyclohexylthio)pyridine(78526-47-3)
• EPA Substance Registry System: 4-(cyclohexylthio)pyridine(78526-47-3)

Safety Data

• Hazardous Substances Data: 78526-47-3(Hazardous Substances Data)

Upstream product

• 98-89-5 Cyclohexanecarboxylic acid 
• 4556-23-4 pyridine-4-thiol 
• 126812-30-4 1,3-dioxoisoindolin-2-yl cyclohexanecarboxylate 
• 1569-69-3 Cyclohexanethiol 
• 15854-87-2 4-iodopyridine 
• 2645-22-9 dipyridin-4-yl disulfide 
• 110-82-7 cyclohexane 
• 78526-32-6 2,6-Dimethyl-4'-p-tolylsulfanyl-4'H-[1,1']bipyridinyl-4-one 
• 78526-28-0 4'-Cyclohexylsulfanyl-2,6-dimethyl-4'H-[1,1']bipyridinyl-4-one 

Relevant articles and documents

Visible-Light-Mediated Alkylation of Thiophenols via Electron Donor-Acceptor Complexes Formed between Two Reactants

A metal-free, photocatalyst-free, photochemical system was developed for the direct alkylation of thiophenols via electron donor-acceptor (EDA) complexes (KEDA = 145 M-1) between two reactants, N-hydroxyphthalimide esters as acceptors and thiophenol anions as donors, in the presence of a tertiary amine. The EDA complexes in the reaction system have a broad range of visible-light absorption (400-650 nm) and can trigger the reaction effectively under sunlight.

CATALYTIC C-X-BOND METATHESIS THROUGH ARYLATION

The present invention refers to a process for a catalytic aryl transfer to rearrange the backbone of aromatic C-X bonds.

Synthetic Applications of N-N Linked Heterocycles. Part 12. The Preparation of 4-Alkylthio- and 4-Arylthio-pyridines by Regiospecific Attack of Thioalkoxide Ions on N-(4-Oxopyridin-1-yl)pyridinium Salts

Thiolate ions add regiospecifically to N-(4-oxopyridin-1-yl)pyridinium salts (2)-(7) to give in good to excellent yields only the 1,4-dihydropyridine adducts (8)-(13), regardless of whether or not the pyridone moiety carries substituents for sterically shielding the 2- and 6-positions of the pyridinium ring.The addition is believed to be thermodynamically controlled.Decomposition of the dihydro-adducts under free-radical conditions, or by pyrolysis, gives good yields of pyridin-4-yl thioethers (14) and (16) though the reaction failed with the 2-methyl adducts (9).An improved synthesis of 6-methyl-4-oxopyran-2-carboxylic acid is also described.