78657-67-7

Basic information

• Product Name: Benzene, 5-methoxy-1,3-dimethyl-2-(2-propenyl)-
• CAS NO: 78657-67-7
• Molecular Formula: C12H16O
• Molecular Weight: 176.258
• Mol File: 78657-67-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 5-methoxy-1,3-dimethyl-2-(2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 5-methoxy-1,3-dimethyl-2-(2-propenyl)-(78657-67-7)
• EPA Substance Registry System: Benzene, 5-methoxy-1,3-dimethyl-2-(2-propenyl)-(78657-67-7)

Safety Data

• Hazardous Substances Data: 78657-67-7(Hazardous Substances Data)

Upstream product

• 106-95-6 allyl bromide 
• 361543-99-9 4-methoxy-2,6-dimethylphenylboronic acid 
• 874-63-5 3,5-dimethylmethoxybenzene 
• 6267-34-1 2-bromo-5-methoxy-1,3-dimethyl-benzene 

Downstream Products

• 73879-09-1 4-(2,2-ethylenedioxyethyl)-3,5-dimethylanisole 
• 70242-39-6 2,6-dimethyl-4-methoxyphenylacetaldehyde 

Relevant articles and documents

Gold-catalyzed allylation of aryl boronic acids: Accessing cross-coupling reactivity with gold

A sp3-sp2 C?C cross-coupling reaction catalyzed by gold in the absence of a sacrificial oxidant is described. Vital to the success of this method is the implementation of a bimetallic catalyst bearing a bis(phosphino)amine ligand. A mechanistic hypothesis is presented, and observable transmetalation, C?Br oxidative addition, and C?C reductive elimination in a model gold complex are shown. We expect that this method will serve as a platform for the development of novel transformations involving redox-active gold catalysts.

Π-CYCLIZATION: THE SYNTHESIS OF (+/-)-SOLAVETIVONE AND (+/-)-HINESOL

A general efficient approach leading to the total synthesis of (+/-)-solavetivone, (+/-)-hinesol, and related spirovetivanes, is described.The process involves stereoselective formation of the asymmetric center at C-7 by ?-cyclisation as a key step.