78739-90-9

Basic information

• Product Name: 3-methyl-3-((phenylthio)methyl)-2,3-dihydrobenzofuran
• Synonyms: 3-methyl-3-((phenylthio)methyl)-2,3-dihydrobenzofuran
• CAS NO: 78739-90-9
• Molecular Weight: 256.368
• Mol File: 78739-90-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-methyl-3-((phenylthio)methyl)-2,3-dihydrobenzofuran(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-3-((phenylthio)methyl)-2,3-dihydrobenzofuran(78739-90-9)
• EPA Substance Registry System: 3-methyl-3-((phenylthio)methyl)-2,3-dihydrobenzofuran(78739-90-9)

Safety Data

• Hazardous Substances Data: 78739-90-9(Hazardous Substances Data)

Upstream product

• 930-69-8 sodium thiophenolate 
• 56182-25-3 1-(2-((2-methylallyl)oxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene 
• 156642-47-6 1-iodo-2-((2-methylallyl)oxy)benzene 
• 156098-13-4 phenyl triisopropylsilyl sulfide 
• 108-98-5 thiophenol 

Relevant articles and documents

Palladium-Catalyzed Carbothiolation via Trapping of the σ-Alkyl Palladium Intermediate with RSTIPS

A palladium-catalyzed carbothiolation via the reaction of a σ-alkyl palladium intermediate with a TIPS thioether is described. It was found that the use of Cs2CO3, (IPr)Pd(allyl)Cl, and a TIPS thioether was key to obtaining alkyl aryl and dialkyl sulfides in high yield through the reaction of a σ-alkyl palladium intermediate. The developed reaction is applicable to a wide range of substrates and thiols.