78812-18-7

Basic information

• Product Name: (bis(p-anisoylimine)glyoxal)nickel⁽⁰⁾
• CAS NO: 78812-18-7
• Molecular Weight: 595.32
• Mol File: 78812-18-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (bis(p-anisoylimine)glyoxal)nickel⁽⁰⁾(CAS DataBase Reference)
• NIST Chemistry Reference: (bis(p-anisoylimine)glyoxal)nickel⁽⁰⁾(78812-18-7)
• EPA Substance Registry System: (bis(p-anisoylimine)glyoxal)nickel⁽⁰⁾(78812-18-7)

Safety Data

• Hazardous Substances Data: 78812-18-7(Hazardous Substances Data)

Upstream product

• 24978-42-5 1,4-bis(4'-methoxyphenyl)-1,4-diazabuta-1,3-diene 
• 28923-39-9 nickel(II) bromide dimethoxyethane 

Relevant articles and documents

Electrochemical Synthesis of the Ni(O)-Diazabutadiene Complexes

The electrochemical reduction of Ni salts in the presence of diazabutadiene ligands (DAB= R-N=CH-CH=N-R, R=t-Bu, o-xylyl, p-anisoyl, p-tolyl) has been studied in DMF by cyclic voltammetry and rotating disc polarography.In solutions containing DAB and halide X-, Ni(II) can be reduced to Ni(DAB)2, and the features of this reduction agree with a mechanism where the second DAB replaces X- in the coordination sphere of Ni only after its reduction to Ni(O).Rather concentrated (ca. 0.1 M) solutions of NiBr2*DME and DAB in DMF have been electrolyzed without a supporting electrolyte, making the isolation of the product Ni(DAB)2 particularly easy.Thus, gram quantities of Ni(DAB)2 can be conveniently prepared within a few hours.