78821-96-2Relevant articles and documents
Synthesis of 1,5- and 1,8-dihydroxyanthraquinones from a common intermediate. A direct synthesis of racemic 7-deoxyaklavinone
Kraus,Chen
, p. 5098 - 5100 (2007/10/02)
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SYNTHESES OF (+/-)-AKLAVINONES. APPLICATION OF THE STEREOCONTROLLED "ZIPPER" BICYCLO-CYCLIZATION REACTION
Uno, Hidemitsu,Naruta, Yoshinori,Maruyama, Kazuhiro
, p. 4725 - 4742 (2007/10/02)
Efficient syntheses of (+/-)-aklavinones; (+/-)-aklavinone (1), (+/-)-auramycinone (2), and (+/-)-13-methylaklavinone (3), are described.A key process of the tetracyclic ring construction in these syntheses is a stereocontrolled "zipper" bicyclo-cyclizati
An Efficient Total Synthesis of (+/-)-Aklavinone
Boeckman, Robert K.,Sum, F.-W.
, p. 4604 - 4610 (2007/10/02)
An 11-step total synthesis of (+/-)-aklavinone from 1,3-cyclohexadione is reported.The key steps include a Diels-Alder condensation of 3 and 4 and the stereoselective aldol condensation of 21 to 22.The overall yield is ca. 13percent.