78956-15-7

Basic information

• Product Name: N-Cyclohexyl-α-phenyl-cinnamid
• Synonyms: N-Cyclohexyl-α-phenyl-cinnamid
• CAS NO: 78956-15-7
• Molecular Weight: 305.42
• Mol File: 78956-15-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-Cyclohexyl-α-phenyl-cinnamid(CAS DataBase Reference)
• NIST Chemistry Reference: N-Cyclohexyl-α-phenyl-cinnamid(78956-15-7)
• EPA Substance Registry System: N-Cyclohexyl-α-phenyl-cinnamid(78956-15-7)

Safety Data

• Hazardous Substances Data: 78956-15-7(Hazardous Substances Data)

Upstream product

• 91-47-4 2,3-diphenylacrylic acid 
• 108-91-8 cyclohexylamine 
• 201230-82-2 carbon monoxide 
• 501-65-5 diphenyl acetylene 
• 886-38-4 diphenylcyclopropenone 

Relevant articles and documents

Copper-catalyzed enantioselective carbonylation toward α-chiral secondary amides

Secondary amides are omnipresent structural motifs in peptides, natural products, pharmaceuticals, and agrochemicals. The copper-catalyzed enantioselective hydroaminocarbonylation of alkenes described in this study provides a direct and practical approach for the construction of α-chiral secondary amides. An electrophilic amine transfer reagent possessing a 4-(dimethylamino)benzoate group was the key to the success. This method also features broad functional group tolerance and proceeds under very mild conditions, affording a set of α-chiral secondary amides in high yields (up to 96% yield) with unprecedented levels of enantioselectivity (up to >99% ee). α,β-Unsaturated secondary amides can also be produced though the method by using alkynes as the substrate.

A novel carbonylative decomplexation of alkyne-dicobalt hexacarbonyls: Hyrocarbamoylation of alkynes

A novel carbonylative decomplexation of alkyne-dicobalt hexacarbonyls, i.e. hydrocarbamoylation of alkynes, was carried out by reaction of the complexes with 10 equiv, of primary and secondary amines.