78960-67-5

Basic information

• Product Name: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-1-phenylnonan-1-one
• Synonyms: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-1-phenylnonan-1-one
• CAS NO: 78960-67-5
• Molecular Weight: 524.177
• Mol File: 78960-67-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-1-phenylnonan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-1-phenylnonan-1-one(78960-67-5)
• EPA Substance Registry System: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-1-phenylnonan-1-one(78960-67-5)

Safety Data

• Hazardous Substances Data: 78960-67-5(Hazardous Substances Data)

Upstream product

• 93-58-3 benzoic acid methyl ester 
• 507-63-1 1-iodoheptadecafluorooctane 
• 52447-23-1 heptadecafluorononanic acid chloride 
• 71-43-2 benzene 
• 100-52-7 benzaldehyde 
• 93-97-0 benzoic acid anhydride 
• 78960-85-7 1-phenyl-2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononan-1-ol 

Relevant articles and documents

Photodecarboxylative Amination of Redox-Active Esters with Diazirines

Diazirines have been recently demonstrated to serve as electrophilic amination reagents that afford diaziridines, versatile heterocycles that are readily transformed into amines, hydrazines, and nitrogen-containing heterocycles. Here, we report the photodecarboxylative amination of redox-active esters with diazirines using inexpensive photoactivators under mild conditions with an enhanced scope for primary substrates. The stability of diazirines to blue light is demonstrated, paving the way for further research into other photochemical amination methods with these unique heterocycles.

PROCESSES AND COMPOUNDS FOR THE DECARBOXYLATIVE AMINATION OF REDOX-ACTIVE ESTERS WITH DIAZIRINES

The invention described herein relates generally to processes for the synthesis of amine-containing organic compounds. More specifically, described herein relates to processes for the decarboxylative amination of redox-active esters with diazirines and the products formed thereof. Compounds for use in the above processes are also described.

Preparation of Perfluoroalkyl Ketones by the Reaction of Perfluoroalkyllithiums with Esters

A variety of esters react with perfluoroalkyllithiums in situ generated from perfluoroalkyl iodides and methyllithium to give perfluoroalkyl ketones in good yields.Perfluoroalkyllithiums add to α,β-unsaturated esters only in the 1,2-addition mode even in the presence of copper salt.Exception was observed in the reaction with maleates where perfluoroalkylated succinic esters and normal 1,2-addition products are obtained in comparable amounts.