79-53-8Relevant articles and documents
3-CHLOROPENTAFLUOROPROPENE-1,2-OXIDE: PREPARATION AND REACTIONS WITH SOME HETEROATOM NUCLEOPHILES AND ANTIMONY PENTAFLUORIDE
Kvicala, J.,Paleta, O.
, p. 6721 - 6724 (1994)
Nucleophilic epoxidation of 3-chloropentafluoro-1-propene at PTC conditions afforded 3-chloropentafluoropropene-1,2-oxide, which was reacted with some oxygen and nitrogen nucleophiles to 3-chloro-3,3-difluoropropionic acid derivatives.With antimony pentafluoride, mixture of fluorinated acetones was obtained.
Preparation of α-halo-F-2-ketones and F-2-ketones via fluorination of α,α-dihalo-F-2-ketones
Burton, Donald J.,Jeong, In Howa
, p. 153 - 156 (2007/10/02)
Fluorination of α,α-dichloro-F-2-ketones with antimony pentafluoride provided excellent yields of α-chloro-F-2-ketones and F-2-ketones regioselectively.However, fluorination of α,α-dibromo-F-2-ketones with antimony pentafluoride gave a mixture of α-bromo-F-2-ketones and F-2-ketones.
REDUCTIVE DEFLUORINATION OF HEXAFLUOROACETONE AND THE SYNTHESIS OF HALOPENTAFLUOROACETONES
Postovoi, S. A.,Vol'pin, I. M.,Mysov, E. I.,Zeifman, Yu. V.,German, L. S.
, p. 1067 - 1070 (2007/10/02)
-