79003-26-2Relevant articles and documents
Selective hydrodeoxygenation of hydroxyacetophenones to ethyl-substituted phenol derivatives using a FeRu?SILP catalyst
Bordet, Alexis,Goclik, Lisa,Leitner, Walter,Offner-Marko, Lisa
supporting information, p. 9509 - 9512 (2020/09/02)
The selective hydrodeoxygenation of hydroxyacetophenone derivatives is achieved opening a versatile pathway for the production of valuable substituted ethylphenols from readily available substrates. Bimetallic iron ruthenium nanoparticles immobilized on an imidazolium-based supported ionic liquid phase (Fe25Ru75?SILP) show high activity and stability for a broad range of substrates without acidic co-catalysts. This journal is
Dynamic Kinetic Resolution for Construction of Three Transannular Stereocenters of Dihydrobenzofuranols
Fang, Lizhen,Zhao, Fangfei,Hu, Shuyu,Han, Lili,Sun, Qianqian,Wu, Huipan,Hu, Xiaojing,Wang, Mingyong
, p. 15569 (2019/03/12)
A handy and effective method was established to obtain the cis-2,3-dihydrobenzofuranols having three stereocenters, involving asymmetric transfer hydrogenation of benzofuranones via dynamic kinetic resolution. The general applicability of this method was examined with different benzofuran-3-(2H)-ones, and stereoselectivities of 85-99% ee and up to 98/2 dr were obtained.
Regioselective synthesis of 5-alkylsalicylates, 5-alkyl-2-hydroxy- acetophenones, and 5-alkyl-2-hydroxy-benzophenones by [3 + 3] cyclization of 1,3-bis(silyl enol ethers) with 2-alkyl-1,1,3,3-tetraethoxypropanes
Mamat, Constantin,Buettner, Stefan,Trabhardt, Tiana,Fischer, Christine,Langer, Peter
, p. 6273 - 6275 (2008/02/10)
(Chemical Equation Presented) A variety of 5-alkylsalicylates, 5-alkyl-2-hydroxy-acetophenones, and 5-alkyl-2-hydroxy-benzophenones was regioselectively prepared by TiCl4 mediated formal [3 + 3] cyclization of 1,3-bis(silyl enol ethers) with 2-alkyl-1,1,3,3- tetraethoxypropanes.
