79121-16-7

Basic information

• Product Name: (S,S)-Hydratropasaeure-1-phenylester
• Synonyms: (S,S)-Hydratropasaeure-1-phenylester
• CAS NO: 79121-16-7
• Molecular Weight: 254.329
• Mol File: 79121-16-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (S,S)-Hydratropasaeure-1-phenylester(CAS DataBase Reference)
• NIST Chemistry Reference: (S,S)-Hydratropasaeure-1-phenylester(79121-16-7)
• EPA Substance Registry System: (S,S)-Hydratropasaeure-1-phenylester(79121-16-7)

Safety Data

• Hazardous Substances Data: 79121-16-7(Hazardous Substances Data)

Upstream product

• 931405-93-5 pentafluorophenyl (S)-2-phenylpropionate 
• 1445-91-6 (S)-1-phenylethanol 
• 98-85-1 1-Phenylethanol 
• 104013-15-2 2-phenylpropionic acid p-nitrophenyl ester 
• 492-37-5 hydratropic acid 
• 219951-25-4 (+/-)-pentafluorophenyl 2-phenylpropionate 
• 25145-43-1 (2S)-2-phenylpropionyl chloride 
• 79121-13-4 (R)-2-phenylpropionic acid-(R)-1-phenylethyl ester 
• 25145-43-1 2-phenylpropionyl chloride 
• 1232774-01-4 (S)-1-methyl-3-(2-phenylpropanoyl)-1H-imidazol-3-ium chloride 
• 7782-24-3 (S)-2-Phenylpropionic acid 
• 938-79-4 (2R)-2-phenylbutanoic acid 
• 60-29-7 diethyl ether 
• 3156-07-8 methyl phenyl ketene 

Downstream Products

• 79121-13-4 2-(RS)-phenylethyl 2-(RS)-phenylpropanoate 
• 7782-24-3 (S)-2-Phenylpropionic acid 
• 7782-26-5 (R)-2-Phenylpropionic acid 

Relevant articles and documents

Parallel kinetic resolution of 1-phenylethanol using quasi-enantiomeric active esters

The parallel kinetic resolution of racemic 1-phenylethanol using an equimolar combination of quasi-enantiomeric pentafluorophenyl esters is discussed. The levels of diastereoselectivity were excellent (>88% de) leading to separable quasi-enantiomeric esters in good yields. Georg Thieme Verlag Stuttgart.

Kinetic resolution of racemic secondary alcohols mediated by N-Methylimidazole in the presence of optically active acyl chlorides

N-Methylimidazole was used to promote the acylation of secondary racemic alcohols and to carry out their kinetic resolution through intermediate chiral acyl imidazolium chlorides. The kinetic resolution could be turned into a catalytic process in the presence of a catalytic amount of N-methylimidazole.

Parallel kinetic resolution of racemic 1-phenylethanol using quasi-enantiomeric combinations of carboxylic acids mediated by N,N′-dicyclohexylcarbodiimide and 3,5-lutidine

The parallel kinetic resolution of racemic 1-phenylethanol using an equimolar combination of quasi-enantiomeric 2-arylpropionic and butanoic acids mediated by a N,N′-dicyclohexylcarbodiimide (DCC)/3,5-lutidine coupling is discussed. The levels of diastereoselectivity were high leading to separable quasi-enantiomeric esters in good yield.