791602-99-8

Basic information

• Product Name: (2E)-4-(tert-butyldiphenylsiloxy)-but-2-enyl methyl carbonate
• Synonyms: (2E)-4-(tert-butyldiphenylsiloxy)-but-2-enyl methyl carbonate
• CAS NO: 791602-99-8
• Molecular Weight: 384.547
• Mol File: 791602-99-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2E)-4-(tert-butyldiphenylsiloxy)-but-2-enyl methyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: (2E)-4-(tert-butyldiphenylsiloxy)-but-2-enyl methyl carbonate(791602-99-8)
• EPA Substance Registry System: (2E)-4-(tert-butyldiphenylsiloxy)-but-2-enyl methyl carbonate(791602-99-8)

Safety Data

• Hazardous Substances Data: 791602-99-8(Hazardous Substances Data)

Upstream product

• 92808-78-1 (E)-4-(tert-butyldiphenylsilyloxy)-2-buten-1-ol 
• 79-22-1 methyl chloroformate 

Downstream Products

• 1087137-02-7 (2E)-benzyl-4-(tert-butyldiphenylsiloxy)but-2-en-1-amine 
• 1099751-82-2 (+)-(2S)-N-benzyl-1-(tert-butyldiphenylsiloxy)but-3-en-2-amine 
• 926659-96-3 (S)-1-((1-(tert-butyldiphenylsilyloxy))but-3-en-2-yl)-4-(4-fluorophenyl)-1H-imidazole 
• 1062291-93-3 methyl (4E)-6-{[tert-butyl(diphenyl)silyl]oxy}-2-{[methoxy(methyl)amino]carbonyl}hex-4-enoate 
• 1062291-87-5 methyl (2S,3R)-3-({[tert-butyl(diphenyl)silyl]oxy}methyl)-2-{[methoxy(methyl)amino]carbonyl}pent-4-enoate 
• 1062291-96-6 methyl (2R,3R)-3-({[tert-butyl(diphenyl)silyl]oxy}methyl)-2-{[methoxy(methyl)amino]carbonyl}pent-4-enoate 

Relevant articles and documents

Enantioselective iridium-catalyzed allylic aminations of allylic carbonates with functionalized side chains. Asymmetric total synthesis of (S)-vigabatrin

Indium-catalyzed aminations of allylic carbonates containing a variety of O-functional groups have been explored. High degrees of regio- as well as enantioselectivity were achieved with diacylamides under salt-free conditions and with arylamines. The results allowed the antiepilepsy drug (5)-vigabatrin to be prepared via a very short route.