79175-78-3

Basic information

• Product Name: 3-(3-Aza-bicyclo[3.2.2]non-3-yl)-2-methyl-1-phenyl-propan-1-one; hydrochloride
• Synonyms: 3-(3-Aza-bicyclo[3.2.2]non-3-yl)-2-methyl-1-phenyl-propan-1-one; hydrochloride
• CAS NO: 79175-78-3
• Molecular Weight: 307.864
• Mol File: 79175-78-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(3-Aza-bicyclo[3.2.2]non-3-yl)-2-methyl-1-phenyl-propan-1-one; hydrochloride(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(3-Aza-bicyclo[3.2.2]non-3-yl)-2-methyl-1-phenyl-propan-1-one; hydrochloride(79175-78-3)
• EPA Substance Registry System: 3-(3-Aza-bicyclo[3.2.2]non-3-yl)-2-methyl-1-phenyl-propan-1-one; hydrochloride(79175-78-3)

Safety Data

• Hazardous Substances Data: 79175-78-3(Hazardous Substances Data)

Upstream product

• 110-88-3 1,3,5-Trioxan 
• 5597-41-1 3-azabicyclo<3.2.2>nonane hydrochloride 
• 93-55-0 1-phenyl-propan-1-one 

Relevant articles and documents

STEREOCHEMISTRY OF AMINOCARBONYL COMPOUNDS-X ; THE INFLUENCE OF THE AMINE MOIETY ON 1-2, 1-5 AND 1-6 ASYMMETRIC INDUCTION IN GRIGNARD ADDITIONS AND HYDRIDE REDUCTIONS

The stereoselectivity of the title reactions due to a hindering amino group in α-asymmetric aminoketones (1 and 2) and to an asymmetric center far away from the reaction center in β-(methylpiperidino)-ketones (11-14) has been studied.The aminoalcohols obtained (3-8 and 15-22) have been separated in most cases and the relative configurations attributed by NMR.Based on diastereomeric ratios, a N-coordinated cyclic transition state has been proposed and is, effective for the Grignard reactions on the β-aminoketone system.