79306-18-6Relevant articles and documents
Magnesium amide-induced pummerer-type reactions of cyclopropyl sulfoxides. Synthesis of cyclopropanone dithioacetals
Kobayashi, Kazuhiro,Horita, Masatoshi,Irisawa, Susumu,Matsunaga, Akihiro,Morikawa, Osamu,Konishi, Hisatoshi
, p. 1367 - 1369 (2002)
The reaction of cyclopropyl phenyl sulfoxide with a magnesium amide, generated from ethylmagnesium bromide and diisopropylamine, gave 1-(phenylthio)cyclopropanol in 72% yield. When the diisopropylmagnesium reagent was treated with a thiol prior to an interaction with cyclopropyl phenyl sulfoxides, symmetrical and unsymmetrical cyclopropanone dithioacetals were produced in fair yields along with small quantities of the corresponding 1-(phenylthio)cyclopropanols.