79345-12-3

Basic information

• Product Name: Benzene, [[(1-methylethoxy)methyl]thio]-
• CAS NO: 79345-12-3
• Molecular Formula: C10H14OS
• Molecular Weight: 182.287
• Mol File: 79345-12-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, [[(1-methylethoxy)methyl]thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[(1-methylethoxy)methyl]thio]-(79345-12-3)
• EPA Substance Registry System: Benzene, [[(1-methylethoxy)methyl]thio]-(79345-12-3)

Safety Data

• Hazardous Substances Data: 79345-12-3(Hazardous Substances Data)

Upstream product

• 7205-91-6 phenylthiomethyl chloride 
• 2388-10-5 lithium isopropoxide 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 67-63-0 isopropyl alcohol 

Relevant articles and documents

Anodic Oxidation of (Trimethylsilyl)methanes with ?-Electron Substituents in the Presence of Nucleophiles

It was found that oxidation potentials of methanes with ?-electron substituents were decreased by introduction of a trimethylsilyl group.The anodic oxidation of benzyl-, allyl-, aryl(or alkyl)thiomethyl-, and aryloxymethyl-substituted trimethylsilanes smoothly proceeded in the presence of nucleophiles, e.g. alcohols and carboxylic acids, to eliminate the trimethylsilyl groups giving the corresponding alkoxylated and carboxylated products in moderate or high yields without full optimization of electrolytic conditions, while aminomethylsilanes did not undergo such a kind of anodic oxidation.

Reaction of Alkoxides with (Phenylthio)carbene: A Novel Oxyanionic Substituent Effect on the C-H Insertion of Carbenes

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