79433-14-0

Basic information

• Product Name: (2Z,6E)-3,7-dimethyl-8-phenylthio-2,6-octadien-1-ol
• Synonyms: (2Z,6E)-3,7-dimethyl-8-phenylthio-2,6-octadien-1-ol
• CAS NO: 79433-14-0
• Molecular Weight: 262.416
• Mol File: 79433-14-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2Z,6E)-3,7-dimethyl-8-phenylthio-2,6-octadien-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2Z,6E)-3,7-dimethyl-8-phenylthio-2,6-octadien-1-ol(79433-14-0)
• EPA Substance Registry System: (2Z,6E)-3,7-dimethyl-8-phenylthio-2,6-octadien-1-ol(79433-14-0)

Safety Data

• Hazardous Substances Data: 79433-14-0(Hazardous Substances Data)

Upstream product

• 930-69-8 sodium thiophenolate 
• 79433-13-9 acetic acid (2Z,6E)-8-bromo-3,7-dimethyl-octa-2,6-dienyl ester 

Relevant articles and documents

Intramolecular Cyclization of Nerol and the Related Attack of (Z)-Allylic Alcohol Moiety on the Terminal Olefin Linkage as Induced by TiCl4-PhNHMe Complex. Synthesis of Nezukone

Nerol was cyclized to terpinyl chloride or bromide in the presence of TiX4-PhNHMe (1:1) complex (I, X=Cl, Br) in dichloromethane at -23 deg C, geraniol being converted into geranyl halide by simple halogenation.Terminally modified derivatives YCH2C(Me)=CHCH2CH2CMe=CHCH2OH (Y=SiMe3, SnBu3) of (2Z,6E) configuration were cyclized by treatment with I to afford limonene in high yields and 100percent selectivity.Cyclization of (2Z) isomers of CH2=CR-CH2CH2CMe=CHCH2OH (R=H, Me, Cl) produced seven-membered carbocyclic products in fair yields.The novel procedure has been utilized in the synthesis of nezukone from (2E)-3-isopropyl-2,6-heptadien-1-ol involving five steps.