79744-76-6Relevant articles and documents
Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(i) complexes bearing triazole ligands
Martínez-Ferraté, Oriol,Chatterjee, Basujit,Werlé, Christophe,Leitner, Walter
, p. 6370 - 6378 (2019)
Manganese(i) complexes bearing triazole ligands are reported as catalysts for the hydrosilylation of carbonyl and carboxyl compounds. The desired reaction proceeds readily at 80 °C within 3 hours at catalyst loadings as low as 0.25 to 1 mol%. Hence, good to excellent yields of alcohols could be obtained for a wide range of substrates including ketones, esters, and carboxylic acids illustrating the versatility of the metal/ligand combination.