79807-58-2

Basic information

• Product Name: Benzene, 1-bromo-2-(2-methoxy-4-nitrophenoxy)-4-nitro-
• CAS NO: 79807-58-2
• Molecular Formula: C13H9BrN2O6
• Molecular Weight: 369.128
• Mol File: 79807-58-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-2-(2-methoxy-4-nitrophenoxy)-4-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-2-(2-methoxy-4-nitrophenoxy)-4-nitro-(79807-58-2)
• EPA Substance Registry System: Benzene, 1-bromo-2-(2-methoxy-4-nitrophenoxy)-4-nitro-(79807-58-2)

Safety Data

• Hazardous Substances Data: 79807-58-2(Hazardous Substances Data)

Upstream product

• 52427-05-1 2-bromo-5-nitrophenol 
• 77337-82-7 1-bromo-2-methoxy-4-nitrobenzene 
• 79807-53-7 potassium 2-bromo-5-nitrophenoxide 

Downstream Products

• 79807-61-7 Potassium; 2-(2-bromo-5-nitro-phenoxy)-5-nitro-phenolate 
• 79807-56-0 2-(2-ethoxy-5-nitrophenoxy)-5-nitrophenol 
• 79819-61-7 2-(2-ethoxy-5-nitrophenoxy)-4-nitrophenol 
• 79807-57-1 2-(2-methoxy-5-nitrophenoxy)-4-nitrophenol 
• 79807-55-9 2-(2-methoxy-5-nitrophenoxy)-5-nitrophenol 
• 71400-34-5 2,8-dinitrodiphenylene dioxide 
• 71400-33-4 2,7-dinitrodibenzo-p-dioxin 
• 79819-62-8 2-(2-bromo-5-nitrophenoxy)-5-nitrophenol 

Relevant articles and documents

The Smiles Rearrangement of 2-Aryloxy-5-nitrophenoxides. Attempted Routes to Benzoxirens and Tribenzotrioxonins

Formation of dibenzo-p-dioxins by the pyrolysis of 2-halogenophenoxides does not appear to involve intermediate benzoxirens.Thermal self-condensation to potassium 2-bromo-5-nitrophenoxide (1b) gave a mixture of 2,7- and 2,8-dinitrobenzo-p-dioxins (6d) and (6e).The mechanism of formation of the 2,8-isomer (6e) is shown to involve Smiles rearrangement of potassium 2-(2-bromo-5-nitrophenoxy)-5-nitrophenoxide (9a).Further examples of Smiles rearrangements of 2-aryloxy-5-nitrophenoxides and an attempted synthesis of the tribenzotrioxonin derivatives (16) are described.