79826-47-4

Basic information

• Product Name: cis-Aquachlorobis(triphenylphosphan)platin(II)-tetrafluoroborat
• CAS NO: 79826-47-4
• Molecular Weight: 859.935
• Mol File: 79826-47-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-Aquachlorobis(triphenylphosphan)platin(II)-tetrafluoroborat(CAS DataBase Reference)
• NIST Chemistry Reference: cis-Aquachlorobis(triphenylphosphan)platin(II)-tetrafluoroborat(79826-47-4)
• EPA Substance Registry System: cis-Aquachlorobis(triphenylphosphan)platin(II)-tetrafluoroborat(79826-47-4)

Safety Data

• Hazardous Substances Data: 79826-47-4(Hazardous Substances Data)

Upstream product

• 67969-82-8 tetrafluoroboric acid diethyl ether 
• 10199-34-5 cis-dichlorobis(triphenylphosphine)platinum(II) 

Relevant articles and documents

Darstellung und Reaktionen von kationischen Chlorobis(phosphan)platin(II)-Komplexen

+BF4- (1) and (R3P)2Pt(Cl)OSO2CF3 (2) have been prepared by abstraction of chloride from cis-(R3P)2PtCl2 using tetrafluoroboric acid or trifluoromethanesulfonic acid, respectively.The protons of the aqua ligand in 1 form hydrogen bridges to the BF4- anion.The acidic complexes 1 and 2 are useful starting materials for new platinum(II) complexes.HCO3- neutralizes 1 to form the carbonato complex (Et3P)2PtO2CO (5).The heterogenous reaction of 2a with glycinate gives the cationic chelate complex (6).The coordinated water of 1 is easily substituted by other ligands, e.g. phosphanes.The chloro-bridged complexes 2+ are formed by treatment of 1 or 2 with ethers.