79827-19-3

Basic information

• Product Name: C₃₂H₃₆O₈Si
• Synonyms: C₃₂H₃₆O₈Si
• CAS NO: 79827-19-3
• Molecular Weight: 576.719
• Mol File: 79827-19-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₂H₃₆O₈Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₂H₃₆O₈Si(79827-19-3)
• EPA Substance Registry System: C₃₂H₃₆O₈Si(79827-19-3)

Safety Data

• Hazardous Substances Data: 79827-19-3(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 22224-41-5 1,3,5-tri-O-benzoyl-α-D-ribofuranoside 

Relevant articles and documents

Synthesis of 2',3'-Differentiated Ribonucleosides via Glycosylation. Reactions with 2-O-Me or 2-O-TBDMS Ribofuranose Derivatives. 1. Pyrimidine Series

The synthesis of 2',3' asymmetrically substituted pyrimidine ribonucleosides in 70-95percent yields by using modified Vorbruggen conditions with "nonparticipating" 2-O-CH3 and 2-O-TBDMS ribofuranoses is described.Such compounds are useful synthons for oligoribonucleotide synthesis, including incorporation of "rare" bases.New and practically useful conditions for placement (using 1,2,4-triazole) and removal (KF/crown ether) of the tert-butyldimethylsilyl (TBDMS) protecting group are also reported.