79963-48-7

Basic information

• Product Name: 1-(p-nitrobenzoyl)ethyl tosylate
• Synonyms: 1-(p-nitrobenzoyl)ethyl tosylate
• CAS NO: 79963-48-7
• Molecular Weight: 349.364
• Mol File: 79963-48-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(p-nitrobenzoyl)ethyl tosylate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(p-nitrobenzoyl)ethyl tosylate(79963-48-7)
• EPA Substance Registry System: 1-(p-nitrobenzoyl)ethyl tosylate(79963-48-7)

Safety Data

• Hazardous Substances Data: 79963-48-7(Hazardous Substances Data)

Upstream product

• 20461-79-4 α-diazo-p-nitropropiophenone 
• 104-15-4 toluene-4-sulfonic acid 
• 62-23-7 4-nitro-benzoic acid 
• 122-04-3 4-nitro-benzoyl chloride 

Relevant articles and documents

The Acid-catalyzed Decomposition of α-Diazo β-Hydroxy Ketones

The proton acid-catalyzed decomposition of 3-aryl-2-diazo-3-hydroxy-1-phenylpropanone (1) gave aryl and hydrogen migration products.The former was the enol-form (2) of 2-aryl-3-phenyl-1,3-propanedione and the latter was the enol- (3) and keto-form (4) of 1-aryl-3-phenyl-1,3-propanedione.The product ratios, 2/(3+4), were affected by the catalysts and solvents used.More polar solvents favored the formation of aryl migration products (2).On the other hand, the BF3-catalyzed decomposition of 1 gave acetylenic ketones as main products along with 2, 3, 4.The TsOH-catalyzed decomposition of 2-diazo-3-hydroxy-3-phenyl-1-indanone, (cyclic α-diazo β-hydroxy ketone), gave 2-phenyl-1,3-indandione quantitatively through phenyl migration.