80255-43-2Relevant articles and documents
A New Type of Silicon-Tin Rearrangement Involving Neighbouring Group Participation of an α-Phosphoryl Group
Sekine, Mitsuo,Kume, Akiko,Hata, Tsujiaki
, p. 969 - 970 (2007/10/02)
Diethyl 1-hydroxy-3-phenyl-1-trimethylsilylpropylphosphonate (5) underwent silicon-tin rearrangement with tributyltin alkoxides to afford the 1-silyloxy-1-stannylpropylphosphonate (6) in high yield; the 1-hydroxypropylphosphonate (8) was converted by treatment with a stannylating agent into the ketone (9).