80287-80-5

Basic information

• Product Name: cis-(3-Methyl-2-oxocyclohexyl)essigsaeure-methylester
• CAS NO: 80287-80-5
• Molecular Weight: 184.235
• Mol File: 80287-80-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-(3-Methyl-2-oxocyclohexyl)essigsaeure-methylester(CAS DataBase Reference)
• NIST Chemistry Reference: cis-(3-Methyl-2-oxocyclohexyl)essigsaeure-methylester(80287-80-5)
• EPA Substance Registry System: cis-(3-Methyl-2-oxocyclohexyl)essigsaeure-methylester(80287-80-5)

Safety Data

• Hazardous Substances Data: 80287-80-5(Hazardous Substances Data)

Upstream product

• 19980-33-7 6-methyl-1-trimethylsiloxycyclohex-1-ene 
• 96-32-2 bromoacetic acid methyl ester 
• 2903-21-1 (3-Methyl-2-oxocyclohexyl)essigsaeure-methylester 

Relevant articles and documents

Fluoride-Mediated Reactions of Enol Silyl Ethers. Regiospecific Monoalkylation of Ketones

Treatment of enol silyl ethers with alkyl halides in the presence of benzyltrimethylammonium fluoride and molecular sieves at room temperature gives the corresponding monoalkylated products with high regiospecificity.In most cases no polyalkylated products formed in the reaction.The alkylation reaction is highly chemospecific: esters, epoxides, and even ketones survive the reaction conditions.The reactions of various cyclohexanone derivatives proceed with the preferential axial attack of the electrophile.