80324-75-0

Basic information

• Product Name: (2S,3S)-2-Hydroxymethyl-3-methyl-3-(4-methyl-pent-3-enyl)-cyclohexanone
• CAS NO: 80324-75-0
• Molecular Weight: 224.343
• Mol File: 80324-75-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3S)-2-Hydroxymethyl-3-methyl-3-(4-methyl-pent-3-enyl)-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-2-Hydroxymethyl-3-methyl-3-(4-methyl-pent-3-enyl)-cyclohexanone(80324-75-0)
• EPA Substance Registry System: (2S,3S)-2-Hydroxymethyl-3-methyl-3-(4-methyl-pent-3-enyl)-cyclohexanone(80324-75-0)

Safety Data

• Hazardous Substances Data: 80324-75-0(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 1193-18-6 3-methylcyclohexen-2-one 
• 37586-57-5 4-methyl-3-pentenylmagnesium bromide 

Downstream Products

• 80324-74-9 C₂₂H₃₃NO₂S 
• 80324-74-9 C₂₂H₃₃NO₂S 
• 80324-74-9 C₂₂H₃₃NO₂S 
• 80324-74-9 C₂₂H₃₃NO₂S 
• 56684-97-0 β-panasinsene 
• 80324-77-2 2-methylene-3-(4-methyl-3-pentenyl)-1-cyclohexanol 

Relevant articles and documents

Photoredox-Catalyzed Cascade Reactions Involving Aryl Radical: Total Synthesis of (±)-Norascyronone A and (±)-Eudesmol

Herein, we have developed two types of photoredox-catalyzed cascade reactions using diaryliodonium salts for the concise synthesis of norascyronone A and β-eudesmol. A rationally designed photoredox-catalyzed arylation/cyclization/Friedel-Crafts cascade reaction of enone was exploited to generate the norascyronone polycyclic skeleton. A visible-light-induced radical cyclization/acyloxy-migration reaction was explored to forge the decalin skeleton of eudesmol, and mechanistic studies indicated the reaction was initiated by one-electron oxidation of the enol ester.