80393-27-7

Basic information

• Product Name: 2-p-Tolyl-indan
• Synonyms: 2-p-Tolyl-indan
• CAS NO: 80393-27-7
• Molecular Weight: 208.303
• Mol File: 80393-27-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-p-Tolyl-indan(CAS DataBase Reference)
• NIST Chemistry Reference: 2-p-Tolyl-indan(80393-27-7)
• EPA Substance Registry System: 2-p-Tolyl-indan(80393-27-7)

Safety Data

• Hazardous Substances Data: 80393-27-7(Hazardous Substances Data)

Upstream product

• 5720-05-8 4-methylphenylboronic acid 
• 95-13-6 1-indene 
• 7561-48-0 2-(4-methylphenyl)indan-1,3-dione 

Relevant articles and documents

Enantioselective Synthesis of Chiral Indane Derivatives by Rhodium-Catalyzed Addition of Arylboron Reagents to Substituted Indenes

Rhodium-catalyzed asymmetric addition of arylboron reagents to indene derivatives proceeded to give 2-arylindanes in good yields with high enantioselectivity. Deuterium-labeling experiments indicated that the present reaction involved a 1,4-Rh shift from an initially formed benzylrhodium to an arylrhodium intermediate before protonation leading to the corresponding addition product. The asymmetric addition was also successful for acenaphthylene, which has a similar skeleton to indene, where it was found that the benzylrhodium intermediate underwent direct protonation without the 1,4-Rh shift.

IONIC HYDROGENATION OF 1,3-INDANEDIONE DERIVATIVES

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