80401-23-6

Basic information

• Product Name: (E)-2-(3-(trimethylsilyl)allyl)cyclohexanone
• Synonyms: (E)-2-(3-(trimethylsilyl)allyl)cyclohexanone
• CAS NO: 80401-23-6
• Molecular Weight: 210.392
• Mol File: 80401-23-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-2-(3-(trimethylsilyl)allyl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(3-(trimethylsilyl)allyl)cyclohexanone(80401-23-6)
• EPA Substance Registry System: (E)-2-(3-(trimethylsilyl)allyl)cyclohexanone(80401-23-6)

Safety Data

• Hazardous Substances Data: 80401-23-6(Hazardous Substances Data)

Upstream product

• 1046204-46-9 2-(2-(2-chlorophenylthio)-3-(trimethylsilyl)propyl)cyclohexanone 
• 31121-19-4 bis(2-chlorobenzene)disulfide 
• 108-94-1 cyclohexanone 
• 7299-28-7 Tri-n-butyltin trifluoroacetate 
• 86422-21-1 (E)-3-(trimethylsilyl)-2-propenyl acetate 
• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 86422-22-2 3-trimethylsilylallyl acetate 

Relevant articles and documents

Radical, one-step approach to o-chlorophenyl thioethers from xanthates. A rapid access to vinylsilanes

(Chemical Equation Presented) Xanthates have been readily converted into o-chlorophenyl thioethers using a one-step procedure conducted under radical conditions. In some selected cases, these aryl thioethers were successfully oxidized to the corresponding sulfoxides and sulfenic acid elimination afforded the corresponding vinylsilanes.

SYNTHESIS OF VINYLSILANES BY PALLADIUM-CATALYZED REACTION OF TRIMETHYLSILYLALLYL ACETATES WITH NUCLEOPHILES

Treatment of 1-trimethylsilylallyl and 3-trimethylsilylallyl acetates with nucleophiles (active methylene compounds and enamines) in the presence of a catalytic amount of Pd(PPh3)4 affords vinylsilane derivatives selectively.