80421-31-4Relevant articles and documents
Uebergangsmetallaktivierte organische Verbindungen, IX. Synthese von Polyfuranen durch metallorganische oxidative Kupplung
Kauffmann, Thomas,Lexy, Herbert,Kriegesmann, Reinhard
, p. 3667 - 3673 (2007/10/02)
2,2'- (2a) and 3,3'-bifuran (3), hitherto only accessible by ring-forming syntheses in small yields, and the unknown compounds all-α-terfuran (2b) and all-α-quaterfuran (2c) have been prepared by convenient ring-connecting syntheses in 85, 46, 16, or 53percent-yield, respectively.Lithiation of 2a and subsequent reacting with iodine afforded 5-iodo-2,2'-bifuran (6b, 46percent).According to competition experiments acidity against n-butyllithium is increasing in the sequence furan 2a 2b.