80496-45-3

Basic information

• Product Name: 1-Phenyl-4-trimethylsilyl-1-butanol
• Synonyms: 1-Phenyl-4-trimethylsilyl-1-butanol;SDK-32;α-(3-Trimethylsilylpropyl)benzenemethanol
• CAS NO: 80496-45-3
• Molecular Weight: 0
• Mol File: 80496-45-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Phenyl-4-trimethylsilyl-1-butanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Phenyl-4-trimethylsilyl-1-butanol(80496-45-3)
• EPA Substance Registry System: 1-Phenyl-4-trimethylsilyl-1-butanol(80496-45-3)

Safety Data

• Hazardous Substances Data: 80496-45-3(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 168143-45-1 (CH₃)3Si(CH₂)3ZrCl(C₅H₅)2 

Relevant articles and documents

Chromium-Catalyzed Linear-Selective Alkylation of Aldehydes with Alkenes

We developed a chromium-catalyzed, photochemical, and linear-selective alkylation of aldehydes with alkylzirconium species generated in situ from a wide range of alkenes and Schwartz's reagent. Photochemical homolysis of the C-Zr bond afforded alkyl radicals, which were then trapped by a chromium complex catalyst to generate the alkylchromium(III) species for polar addition to aldehydes. The reaction proceeded with high functional group tolerance at ambient temperature under visible-light irradiation.