80511-85-9

Basic information

• Product Name: 1-((trimethylsilyl)ethynyl)cyclohexyl acetate
• Synonyms: 1-((trimethylsilyl)ethynyl)cyclohexyl acetate
• CAS NO: 80511-85-9
• Molecular Weight: 238.402
• Mol File: 80511-85-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-((trimethylsilyl)ethynyl)cyclohexyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-((trimethylsilyl)ethynyl)cyclohexyl acetate(80511-85-9)
• EPA Substance Registry System: 1-((trimethylsilyl)ethynyl)cyclohexyl acetate(80511-85-9)

Safety Data

• Hazardous Substances Data: 80511-85-9(Hazardous Substances Data)

Upstream product

• 1066-54-2 trimethylsilylacetylene 
• 108-94-1 cyclohexanone 
• 17962-22-0 1-((trimethylsilyl)ethynyl)cyclohexanol 
• 108-24-7 acetic anhydride 
• 75-77-4 chloro-trimethyl-silane 
• 5240-32-4 1-acetoxy-1-ethynyl cyclohexane 

Downstream Products

• 1262149-39-2 C₁₀H₁₆O₂⁽¹⁸⁾O 
• 1123-27-9 1-(1-hydroxycyclohexyl)ethan-1-one 
• 52789-73-8 acetic acid 1-acetyl-cyclohexyl ester 
• 5240-32-4 1-acetoxy-1-ethynyl cyclohexane 
• 72335-58-1 1-ethynyl-1-cyclohexyl-carboxylic acid 

Relevant articles and documents

Cobalt-catalyzed carboxylation of propargyl acetates with carbon dioxide

The cobalt-catalyzed carboxylation of propargyl acetates with CO2 (1 atm) is described. The reaction proceeds at room temperature in the presence of Mn powder as a reducing reagent. Various propargyl acetates are converted to the corresponding carboxylic acids in good to high yields.

Use of 1,8-Diazabicycloundec-7-ene in Preparation of Trimethylsilyl Enol Ethers and Trimethylsilylacetylenes

Trimethylsilyl enol ethers were prepared by using a combination of chlorotrimethylsilane and 1,8-diazabicycloundec-7-ene in good yields.Trimethylsilylation of acetylenes was also achieved with the same reagents in the presence of silver salt as catalyst.