80516-36-5Relevant articles and documents
STERIC AND ELECTRONIC LIMITATIONS OF THE SRN1 REACTION BETWEEN p-NITROBENZYLIC SUBSTRATES AND TERTIARY CARBANIONS
Jacobs, Bruce D.,Kwon, Soon-Jae,Field, Leslie D.,Norris, Robert K.,Randles, David,et al.
, p. 3495 - 3498 (2007/10/02)
The SRN1 reaction between sterically hindered p-nitrobenzylic substrates and tertiary carbanions gives C-alkylated products whose yields depend on the steric bulk of both the benzylic substrate and the carbanion, and on the nature of the groups in the carbanion.
Regiochemistry of the Association Step in SRN1 Reactions; Kinetically Controlled Coupling of aci-Nitronate Ions and p-Nitrobenzylic Radicals
Norris, Robert K.,Randles, David
, p. 1047 - 1051 (2007/10/02)
The regiochemistry of the coupling between p-nitrobenzylic radicals and aci-nitronate ions in the association step of SRN1 reactions is shown to be dependent on steric factors.Branching at the carbon which is α to the reaction site causes a shi