805316-34-1

Basic information

• Product Name: (E)-N-(4-methoxybenzylidene)-1,1-diphenylmethanamine
• Synonyms: (E)-N-(4-methoxybenzylidene)-1,1-diphenylmethanamine
• CAS NO: 805316-34-1
• Molecular Weight: 301.388
• Mol File: 805316-34-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (E)-N-(4-methoxybenzylidene)-1,1-diphenylmethanamine(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N-(4-methoxybenzylidene)-1,1-diphenylmethanamine(805316-34-1)
• EPA Substance Registry System: (E)-N-(4-methoxybenzylidene)-1,1-diphenylmethanamine(805316-34-1)

Safety Data

• Hazardous Substances Data: 805316-34-1(Hazardous Substances Data)

Upstream product

• 2393-23-9 4-methoxy-benzylamine 
• 91-00-9 Benzhydrylamine 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 108860-27-1 4-p-methoxybenzoyloxy-3,4-di(p-methoxyphenyl)-1,1-diphenyl-2-azabuta-1,3-diene 
• 107836-62-4 2-benzhydryl-3-(4-methoxyphenyl)-1,2-oxaziridine 
• 1283154-30-2 N-benzhydryl-1-[dimethyl(phenyl)silyl]-1-(4-methoxyphenyl)methanamine 
• 108893-53-4 4-benzoyloxy-3-(p-methoxyphenyl)-1,4,4-triphenyl-2-azabuta-1,3-diene 
• 78999-89-0 N-(diphenylmethylene)-1-(4-methoxyphenyl)methanamine 

Relevant articles and documents

Direct Vinylogous Mannich-Type Reactions via Ring Opening and Rearrangement of Vinyloxiranes

(Matrix presented) The first synthetic application of 2-methyl-2- vinyloxirane as a masked dienolate has been successfully demonstrated in the direct vinylogous Mannich-type reaction with an α-imino ester as an electrophile. The Mannich adduct was a usefu

Activation of the Si-B Linkage: Copper-Catalyzed addition of nucleophilic silicon to imines

Activation of the Si-B bond through copper-catalyzed transmetalation quickly developed into a practical method to generate Cu-Si reagents These silicon nucleophiles cleanly add to aldehyde-derived imine electrophiles to form R-silylated amines in protic media, and no carbon-tonitrogen Brook-type rearrangement of the intermediate anion is observed. Aside from electron-withdrawing groups at the imine nitrogen atom, for example, SO2Tol and P(O)Ph2, previously delicate nitrogen substituents such as phenyl or benzhydryl are tolerated. The same protocol also allows the unprecedented addition to representative ketone-derived imines.

Asymmetric Strecker reaction of N-benzhydrylimines utilising new tropos biphenyldiol-based ligands

The synthesis of a library of N-arenesulfonyl-1,3-oxazolidinyl-substituted biphenyldiols is presented. A set of two central intermediates together with easily accessible N-arenesulfonylamino alcohols furnish a broad variety of 1,3-oxazolidines. These are applied as chiral tropos ligands in a titanium-mediated Strecker-type reaction of N-benzhydrylimines. A correlation between the ee values in the product and the diastereomeric ratio concerning the chiral axis of the ligand is made. Those substituents in the ligand which proved to lead to a higher preference for one diastereomeric conformer of the chiral axis in related compounds now provide the most selective ligands. Two privileged ligands are identified that afford superior results in 8 of 13 screenings. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.