80621-70-1

Basic information

• Product Name: 4-chloro-1-(1,2-dimethoxyethyl)benzene
• CAS NO: 80621-70-1
• Molecular Weight: 200.665
• Mol File: 80621-70-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 4-chloro-1-(1,2-dimethoxyethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-chloro-1-(1,2-dimethoxyethyl)benzene(80621-70-1)
• EPA Substance Registry System: 4-chloro-1-(1,2-dimethoxyethyl)benzene(80621-70-1)

Safety Data

• Hazardous Substances Data: 80621-70-1(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 1073-67-2 4-vinylbenzyl chloride 
• 149-73-5 trimethyl orthoformate 
• 124-41-4 sodium methylate 
• 32294-60-3 diphenyl ditelluride 

Relevant articles and documents

ELECTROOXIDATIVE REARRANGEMENT OF CONJUGATED ARYLOLEFINS TO ARYLACETALDEHYDE DIMETHYL ACETALS

Electrochemical oxidation of conjugated arylolefins 1 in trimethyl orthoformate containing iodine gave arylacetaldehyde dimethyl acetals 2 in high yields.

Effective Au(III)-CuCl2-catalyzed addition of alcohols to alkenes

Alkenes can be activated by Au(III) catalysts, and the effective addition of alcohols to alkenes can be carried out under mild conditions with Au(III), provided that catalytic amounts of CuCl2 are added, which significantly stabilize the cationic Au(III). The Royal Society of Chemistry.

Photochemical Electron-transfer Reaction between Aromatic Olefins and Metal Ions. Dependence of the Reaction Course on the Structure of the Olefins

To investigate the photochemical electron transfer from aromatic olefins to copper(II) or iron(III) ions, a series of substituted styrenes (1) was irradiated in the presence of copper(II) or iron(II) salts in methanol, which gave dimethoxylated monomers (2) and one or more of three types of dimethoxylated dimers .The formation of these products are reasonably attributed to the participation of hte cation radicals of the olefins generated by electron transfer from excited olefins to the methal ions.Substituents on the substrates are found to govern the reaction products.