80659-97-8

Basic information

• Product Name: 5,10,15,20-tetrakis(o-cyanophenyl)porphyrin
• CAS NO: 80659-97-8
• Molecular Weight: 714.788
• Mol File: 80659-97-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 5,10,15,20-tetrakis(o-cyanophenyl)porphyrin(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10,15,20-tetrakis(o-cyanophenyl)porphyrin(80659-97-8)
• EPA Substance Registry System: 5,10,15,20-tetrakis(o-cyanophenyl)porphyrin(80659-97-8)

Safety Data

• Hazardous Substances Data: 80659-97-8(Hazardous Substances Data)

Upstream product

• 109-97-7 pyrrole 
• 7468-67-9 o-formylbenzonitrile 

Downstream Products

• 123811-58-5 5,10,15,20-tetrakis(o-(N-tert-butylcarbamoyl)phenyl)porphyrin 
• 123811-57-4 2,2′,2″,2?-(porphine-5,10,15,20-tetrayl)tetrakis(methyl benzoate) 
• 70152-55-5 α,α,α,α-meso-tetra(o-carboxyphenyl)porphyrin 

Relevant articles and documents

5,10,15,20-Tetrakis(α,α,α,α-o-(N-tert-butylcarbamoyl)phenyl)porphyrin: Synthesis and Redox Properties of Zinc(II) and Copper(II) Complexes

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A Supramolecular Palladium Catalyst Displaying Substrate Selectivity by Remote Control

Inspired by enzymes such as cytochrome P-450, the study of the reactivity of metalloporphyrins continues to attract major interest in the field of homogeneous catalysis. However, little is known about benefitting from the substrate-recognition properties of porphyrins containing additional, catalytically relevant active sites. Herein, such an approach is introduced by using supramolecular ligands derived from metalloporphyrins customized with rigid, palladium-coordinating nitrile groups. According to different studies (NMR and UV/Vis spectroscopy, XRD, control experiments), the supramolecular ligands are able to accommodate pyridine derivatives as substrates inside the porphyrin pocket while the reactivity occurs at the peripheral side. By simply tuning a remote metal center, different binding events result in different catalyst reactivity, and this enzyme-like feature leads to high degrees of substrate selectivity in representative palladium-catalyzed Suzuki–Miyaura reactions.

Synthesis and Kinetic Investigation of the Atropisomerization of meso-Tetra(2-cyanophenyl)porphine

Tetra(2-cyanophenyl)porphine (ToCNPP) has been synthesized and isolated into the four respective atropisomers.The rotation of a cyanophenyl ring about the bond to the methine carbon of the porphyrin leads to interconversion reactions among the isomers.The