80759-05-3Relevant articles and documents
AN APPROACH TO THE MECHANISM OF PHOTOOXIDATION OF BERBERINE UNDER BASIC CONDITIONS
Contreras, M. Leonor,Rivas, Sergio,Rozas, Roberto
, p. 101 - 106 (2007/10/02)
The unsensitized photooxidation of berberine (1) catalyzed by basic reagents such as -SC6H13, -N3, Et3N, -OCH3 or -OC2H5, in solution, is described.As a possible mechanism, the formation of an initial berberine-oxygen exciplex followed by a nucleophilic a