807616-80-4

Basic information

• Product Name: 2-Cyclohexen-1-ol, 1-[4-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phenyl]-
• CAS NO: 807616-80-4
• Molecular Formula: C19H30O2Si
• Molecular Weight: 318.531
• Mol File: 807616-80-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-ol, 1-[4-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-ol, 1-[4-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phenyl]-(807616-80-4)
• EPA Substance Registry System: 2-Cyclohexen-1-ol, 1-[4-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phenyl]-(807616-80-4)

Safety Data

• Hazardous Substances Data: 807616-80-4(Hazardous Substances Data)

Upstream product

• 930-68-7 cyclohexenone 
• 87736-74-1 4-(tert-butyldimethylsiloxymethyl)bromobenzene 

Downstream Products

• 1234577-38-8 benzyl (RS)-{3-[4'-(tert-butyldimethylsilyloxymethyl)phenyl]cyclohex-2-en-1-yl}carbamate 
• 807616-78-0 1-[4-((tert-butyldiphenylsilyloxy)methyl)phenyl]-2-cyclohexen-1-ol 
• 807616-74-6 1-(4-acetoxymethylphenyl)-2-cyclohexen-1-ol 
• 807617-15-8 1-(4-hydroxymethylphenyl)-2-cyclohexen-1-ol 

Relevant articles and documents

Syntheses of trans -SCH-A and cis -SCH-A via a stereodivergent cyclopropanation protocol

(Figure Presented) A highly diastereoselective cyclopropanation protocol has been employed in the syntheses of trans-SCH-A and cis-SCH-A. This strategy encompasses a stereodivergent procedure for the preparation of syn- and anti-cyclopropane diastereoisom

Oxidative rearrangement of tertiary allylic alcohols employing oxoammonium salts

(Chemical Equation Presented) Practical and highly efficient methods for oxidative rearrangement of tertiary allylic alcohols to β-substituted α,β-unsaturated carbonyl compounds employing oxoammonium salts are described. The methods developed are applicable to acyclic substrates as well as medium membered ring substrates and macrocyclic substrates. The counteranion of the oxoammonium salt plays crucial roles on this oxidative rearrangement.