80793-21-1Relevant articles and documents
Transition metal complexes bearing NHC ligands substituted with secondary polyfluoroalkyl groups
Kola?íková,?im?nek,Rybá?ková,Cva?ka,B?ezinová,Kví?ala
, p. 19663 - 19673 (2015/11/27)
Using three different approaches, racemic 1-(perfluoroalkyl)ethylamines were synthesized from perfluoroalkyl iodides or perfluoroalkanoic acids, and further transformed to the corresponding N,N′-disubstituted ethane-1,2-diimines and ethane-1,2-diamines as mixtures of diastereoisomers. Their cyclization afforded imidazolium or dihydroimidazolium salts, which led to silver or palladium complexes bearing NHC ligands substituted with secondary polyfluoroalkyl groups. The palladium complexes bearing a throwaway 3-chloropyridine ligand proved to be moderately active in the model Suzuki-Miyaura coupling.
Reactivity of perfluorohexyl iodide with N,N-disubstituted amides and esters in the presence of a metal couple and radical initiator
Benefice-Malouet, S.,Commeyras, A.
, p. 103 - 108 (2007/10/02)
The reactivity of perfluorohexyl iodide with N,N-disubstituted amides or ethyl formate as solvents and reactants, in the presence of a zinc-copper metal couple and radical initiator, has been investigated.In each case, the corresponding perfluorinated carbonyl compounds, such as aldehydes, amides, ketones and esters, were obtained in good yield, thus proving the efficacy of this reaction.The influence of the radical initiator on the reaction mechanisms has been studied and is discussed. - Keywords: Reactivity; Perfluorohexyl iodide; Disubstituted amines; Zinc-copper metal couple; Radical initiator; NMR spectroscopy; IR spectroscopy; Mass spectrometry
REACTION OF METHYLMAGNESIUM IODIDE WITH PERFLUOROCARBOXYLATE ESTERS
Batizat, D. V.,Yarosh, A. A.,Ignatenko, A. V.,Ponomarenko, V. A.
, p. 1022 - 1024 (2007/10/02)
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