808771-27-9

Basic information

• Product Name: (R)-5-[(Z)-4-(4-Methoxy-benzyloxy)-but-2-enyl]-4-methyl-5H-furan-2-one
• Synonyms: (R)-5-[(Z)-4-(4-Methoxy-benzyloxy)-but-2-enyl]-4-methyl-5H-furan-2-one
• CAS NO: 808771-27-9
• Molecular Weight: 288.343
• Mol File: 808771-27-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-5-[(Z)-4-(4-Methoxy-benzyloxy)-but-2-enyl]-4-methyl-5H-furan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-5-[(Z)-4-(4-Methoxy-benzyloxy)-but-2-enyl]-4-methyl-5H-furan-2-one(808771-27-9)
• EPA Substance Registry System: (R)-5-[(Z)-4-(4-Methoxy-benzyloxy)-but-2-enyl]-4-methyl-5H-furan-2-one(808771-27-9)

Safety Data

• Hazardous Substances Data: 808771-27-9(Hazardous Substances Data)

Upstream product

• 141-78-6 ethyl acetate 
• 808771-26-8 (Z)-(R)-7-(4-Methoxy-benzyloxy)-3-triisopropylsilanyloxy-hept-5-en-2-one 
• 808771-24-6 1-[6-(tert-butyl-dimethyl-silanyloxy)-5-triisopropylsilanyloxy-hex-2-ynyloxymethyl]-4-methoxy-benzene 
• 808771-40-6 1-[(Z)-(R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-triisopropylsilanyloxy-hex-2-enyloxymethyl]-4-methoxy-benzene 
• 808771-25-7 (Z)-(R)-6-(4-Methoxy-benzyloxy)-2-triisopropylsilanyloxy-hex-4-en-1-ol 
• 808771-41-7 (Z)-(R)-7-(4-Methoxy-benzyloxy)-3-triisopropylsilanyloxy-hept-5-en-2-ol 
• 808771-39-3 (2R)-1-(tert-butyldimethylsiloxy)-6-(4-methoxybenzyloxy)-hex-4-yn-2-ol 
• 4039-83-2 3-(4-methoxybenzyloxy)propyne 

Downstream Products

• 11076-19-0 bongkrekic acid 
• 808771-31-5 (R)-5-{(2Z,4E,8E,12E,14Z)-(S)-7-Benzenesulfonyl-16-(tert-butyl-dimethyl-silanyloxy)-14-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-11-methyl-hexadeca-2,4,8,12,14-pentaenyl}-4-methyl-5H-furan-2-one 
• 808771-35-9 (2E,4Z,8Z,10E,14E,18E,20Z)-(6R,17S)-20-(2-Hydroxy-ethyl)-6-methoxy-2,5,17-trimethyl-docosa-2,4,8,10,14,18,20-heptaenedioic acid 1-tert-butyl ester 22-(tert-butyl-diphenyl-silanyloxymethyl) ester 
• 808771-36-0 (2E,4Z,8Z,10E,14E,18E,20Z)-(6R,17S)-20-Carboxymethyl-6-methoxy-2,5,17-trimethyl-docosa-2,4,8,10,14,18,20-heptaenedioic acid 1-tert-butyl ester 22-(tert-butyl-diphenyl-silanyloxymethyl) ester 

Relevant articles and documents

Total synthesis of (+)-bongkrekic acid

Total synthesis of bongkrekic acid, an important apoptosis inhibitor, has been accomplished. The strategy includes inexpensive starting materials, asymmetric alkylation, anionic allyl coupling and oxidative manipulations. This process would provide a sufficient amount of bongkrekic acid and its analogues.