80985-31-5

Basic information

• Product Name: lithium 1-(fluoren-9-yl)cyclohexanolate
• Synonyms: lithium 1-(fluoren-9-yl)cyclohexanolate
• CAS NO: 80985-31-5
• Molecular Weight: 270.3
• Mol File: 80985-31-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: lithium 1-(fluoren-9-yl)cyclohexanolate(CAS DataBase Reference)
• NIST Chemistry Reference: lithium 1-(fluoren-9-yl)cyclohexanolate(80985-31-5)
• EPA Substance Registry System: lithium 1-(fluoren-9-yl)cyclohexanolate(80985-31-5)

Safety Data

• Hazardous Substances Data: 80985-31-5(Hazardous Substances Data)

Upstream product

• 82438-50-4 9-fluorenyllithium 
• 108-94-1 cyclohexanone 
• 881-04-9 9H-fluoren-9-yllithium 

Downstream Products

• 881-04-9 9H-fluoren-9-yllithium 
• 108-94-1 cyclohexanone 

Relevant articles and documents

REACTIVITY OF CARBANIONS. XI. REACTIONS OF ALKALINE SALTS OF FLUORENE AND 9-PHENYLFLUORENE WITH CYCLOHEXANONE

The reaction of alkali (Li, Na, K, and Cs) and tetrabutylammonium salts of fluorene and of lithium salt of 9-phenylfluorene with cyclohexanone was studied in dimethoxyethane, ether, benzene, and hexamethylphosphorotriamide.The reaction proceeds to give both addition and enolization.The reaction is an equilibrium process as shown by a study of the reverse reactions: decomposition of the alcoholate and the reactions of the alkaline enolates of cyclohexanone with fluorene.The position of the equilibrium is very sensitive to the nature of the cation and the solvent and the carbanion structure.The possible causes for this effect are considered.