81-33-4

Basic information

• Product Name: 3,4,9,10-Perylenetetracarboxylic diimide
• Synonyms: 3,4,9,10-PERYLENETETRACARBOXYLIC ACID DIIMIDE;3,4,9,10-PERYLENETETRACARBOXYLIC DIIMIDE;C.I. Pigment Violet 29;Perylene-3,4,9,10-tetraformyldiimine;C.I.Pigment Purple 29;3,4:9,10-Perylenebis(dicarbimide);Anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline 1(2H),3,8(9H),10-tetrone;Anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1(2H),3,8(9H),10-tetrone
• CAS NO: 81-33-4
• Molecular Formula: C₂₄H₁₀N₂O₄
• Molecular Weight: 390.35
• EINECS: 201-344-6
• Product Categories: Fluorenes, etc. (reagent for high-performance polymer research);Functional Materials;Reagent for High-Performance Polymer Research;Reagents for Conducting Polymer Research;OTFT/OFET/OPV Materials;OLED;Intermediates of Dyes and Pigments;Organics;Acid Anhydrides, etc. (Reagents for Conducting Polymer Research);Electroluminescence
• Mol File: 81-33-4.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 821.4 °C at 760 mmHg
• Flash Point: 314 °C
• Appearance: /Powder
• Density: 1.68 g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.88
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility: Sulfuric Acid (Slightly)
• PKA: 8.75±0.20(Predicted)
• Water Solubility: Insoluble in water.
• CAS DataBase Reference: 3,4,9,10-Perylenetetracarboxylic diimide(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,9,10-Perylenetetracarboxylic diimide(81-33-4)
• EPA Substance Registry System: 3,4,9,10-Perylenetetracarboxylic diimide(81-33-4)

Safety Data

• Safety Statements: 22-24/25
• TSCA: Yes
• Hazardous Substances Data: 81-33-4(Hazardous Substances Data)

Usage

Description

3,4,9,10-Perylenetetracarboxylic diimide (PTCDI) is a dark yellow-red to black solid that is a tetracarboxylic diimide derivative of perylene. It is known for its reddish appearance, heat resistance up to 300°C, light fastness of 8, and good acid and alkali resistance.

Uses

Used in Chemical Research:
3,4,9,10-Perylenetetracarboxylic diimide is used as a research compound for various chemical studies.
Used in Industrial Pigments:
PTCDI is used extensively as an industrial pigment due to its reddish shade and high tinting strength of 100-105%.
Used as Tunable Laser Dye:
3,4,9,10-Perylenetetracarboxylic diimide is used as a tunable laser dye in various applications.
Used as Light-Harvesting Material:
PTCDI is used as a light-harvesting material in solar energy applications.
Used in Transistors:
3,4,9,10-Perylenetetracarboxylic diimide is used in the development of transistors.
Used as Molecular Switches:
PTCDI is used in the design of molecular switches for various applications.
Used in Solar Cells:
3,4,9,10-Perylenetetracarboxylic diimide is used in the development of solar cells.
Used in Optoelectronic Devices:
PTCDI is used in the creation of optoelectronic devices.
Used in DNA Triplex Formation:
Planar peryleneand naphthalene-based diimide linkers, such as PTCDI, can be employed to tether the Watson-Crick and Hoogsteen strands of a DNA triplex, providing conjugates capable of targeting single-stranded nucleic acids with the formation of hairpin triplexes.

Flammability and Explosibility

Notclassified

TEST ITEMS

SPECIFICATION

HEAT RESISTANCE

300 °C min

LIGHT FASTNESS

8

ACID RESISTANCE

5

ALKALI RESISTANCE

5

FASTNESS TO BLEEDING

5

SPECIFIC SURFACE

28 m 2 /g

DENSITY

1.60 g/cm 3

RESIDUE ON 80 MESH

5.0% max

VOLATITE 105 °C

1.0% max

InChI:InChI=1/C25H18N6O4/c26-21(27)11-4-1-9-8-2-5-12(23(30)32)19-13(24(31)33)6-3-10(16(8)19)17-15(25(34)35)7-14(22(28)29)18(11)20(9)17/h1-7H,(H3,26,27)(H3,28,29)(H2,30,32)(H2,31,33)(H,34,35)

Upstream product

• 81-83-4 1,8-Naphthalimide 
• 81-32-3 perylene-3,4,9,10-tetracarboxylic acid 
• 52534-87-9 1,3,1',3'-Tetraoxo-2,3,2',3'-tetrahydro-1H,1'H-[6,6']bi[benzo[de]isoquinolinyl]-7,7'-dicarboxylic acid 
• 128-69-8 perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride 
• 64-17-5 ethanol 
• 208-96-8 acenaphthylene 
• 81-84-5 1,8-Naphthalic anhydride 
• 83-32-9 acenaphthene 

Downstream Products

• 81-32-3 perylene-3,4,9,10-tetracarboxylic acid 
• 41572-86-5 N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide 
• 215297-21-5 N-2-[(2-O-4,4′-dimethoxytritylethoxy)ethyl]-N′-2-(2-hydroxyethoxy)ethyl-3,4,9,10-perylenetetracarboxylic diimide 
• 112100-07-9 bis(2,6-diisopropylphenyl)-5,6,12,13-tetraphenoxyanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H, 9H)-tetraone 
• 128-69-8 perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride 
• 6364-19-8 3,9-perylene dicarboxylic acid 

Relevant articles and documents

High-performance black color paste and preparation method thereof

The invention relates to the technical field of black pigments, in particular to a high-performance black color paste and a preparation method thereof. The preparation process does not need to be subjected to grinding treatment, can be highly dispersed in the low-melting-point amphiphilic solid, can effectively improve the workability and repeatability, and reduces the chromatic aberration 10% - 1000%. The preparation method disclosed by the invention causes the components to react and discolor in the kneading machine, finally obtains the black color paste, and is simple in preparation step, easy and convenient to operate, easy to prepare and good in application prospect.

A 3, 9 - perylene dicarboxylic acid preparation method

The invention discloses a 3, 9 - perylene dicarboxylic acid of preparation method, specific step is ice-acetic acid in a solvent, in the dihydro e is obtained under the action of the sodium dichromate of 1, 8 - naphthalenedicarboxylic anhydride; 1, 8 - naphthalenedicarboxylic anhydride in saturated ammonia under the action of the acylation to obtain the 1, 8 - naphthalene asia amide; 1, 8 - naphthalene asia amide in potassium hydroxide and anhydrous sodium acetate manufacturing of the alkaline environment in the alkaline environment in C - C under high-temperature conditions obtained by coupling the 3, 4, 9, 10 - perylenetetracarboxylic acid diimide; 3, 4, 9, 10 - perylenetetracarboxylic acid diimide in under the action of the strong acid is converted into the 3, 4, 9, 10 - [...]; 3, 4, 9, 10 - [...] in microwave reactor in alkaline hydrolysis by the decarboxylation of 3, 9 - perylene dicarboxylic acid. The invention synthetic process more economic, environmental protection, high-efficient and simple.

Preparation method and application of novel perylene acid medicinal molecule with antineoplastic activity

The invention discloses a preparation method and application of a novel perylene acid medicinal molecule with antineoplastic activity, and belongs to the technical field of pharmaceutical synthesis. The novel perylene acid medicinal molecule with antineoplastic activity is characterized by having the structural formula as shown in the description. The invention also provides a preparation method of the novel perylene medicinal molecule with the antineoplastic activity. The prepared perylene medicinal molecule has higher inhibiting activity for human cervical carcinoma Hela cells, human breastcancer MDA-MB-231 cells and human liver cancer HepG2 cells, and has the potential of becoming an antineoplastic medicament.