81055-91-6

Basic information

• Product Name: 2-methyl-2-prop-2-en-1-yl-1H-indene-1,3(2H)-dione
• Synonyms: 1H-Indene-1,3(2H)-dione, 2-methyl-2-(2-propen-1-yl)-; 2-Methyl-2-(prop-2-en-1-yl)-1H-indene-1,3(2H)-dione; 81055-91-6
• CAS NO: 81055-91-6
• Molecular Formula: C₁₃H₁₂O₂
• Molecular Weight: 200.2332
• Mol File: 81055-91-6.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 321.8°C at 760 mmHg
• Flash Point: 120.5°C
• Density: 1.117g/cm³
• Vapor Pressure: 0.000291mmHg at 25°C
• Refractive Index: 1.549
• CAS DataBase Reference: 2-methyl-2-prop-2-en-1-yl-1H-indene-1,3(2H)-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-2-prop-2-en-1-yl-1H-indene-1,3(2H)-dione(81055-91-6)
• EPA Substance Registry System: 2-methyl-2-prop-2-en-1-yl-1H-indene-1,3(2H)-dione(81055-91-6)

Safety Data

• Hazardous Substances Data: 81055-91-6(Hazardous Substances Data)

Upstream product

• 876-83-5 2-methyl-indan-1,3-dione 
• 106-95-6 allyl bromide 

Downstream Products

• 690660-58-3 2-methyl-2-(4-oxo-4-phenylbut-2-enyl)indan-1,3-dione 

Relevant articles and documents

Enantioselective synthesis of fused heterocycles with contiguous stereogenic centers by chiral phosphoric acid catalyzed symmetry breaking

Described herein is a highly enantioselective synthesis of fused piperidine and pyrrolidine derivatives with all-carbon stereogenic centers. The enantioselective reductive amination from Cs-symmetric 1,3-dione derivatives proceeded in a highly stereoselective manner by taking advantage of the desymmetrization approach to afford fused heterocycles with contiguous stereogenic centers in good to excellent enantioselectivities (up to 98% ee).