81077-94-3Relevant articles and documents
Reductive Debromination and Coupling Reaction in the Thermolysis of 5-Bromouracils in N,N-Dialkylamides. Cleavage of the C(5)-Bromine bond by an Initial Electron-transfer Process
Sako, Magiochi,Suzuki, Mikio,Tanabe, Miyuki,Maki, Yoshifumi
, p. 3114 - 3117 (2007/10/02)
Thermolysis of various 5-bromouracils (1) in N,N-dialkylamides results in the formation of methylenebisuracils (2) and reductive debrominated products (3) via cleavage of the C(5)-Br bond; the latter involves a one-electron transfer process.The product distribution between (2) and (3) depends upon the nature of substituents in the uracil ring.