81129-27-3Relevant articles and documents
Enantiospecific Total Synthesis and Absolute Configuration Assignment of Chabrolobenzoquinone H
Koumbis, Alexandros E.,Ouzounthanasis, Konstantinos A.,Rizos, Stergios R.
, p. 1313 - 1324 (2022/01/12)
Chabrolobenzoquinone H (1), a meroditerpene metabolite with cytotoxic activity, is synthesized via a stereoselective Julia–Kocienski olefination between a chiral pool derived aliphatic PT-sulfone and a benzoquinone aldehyde partner. The latter was obtaine