81174-93-8Relevant articles and documents
A Versatile Metathesis Reaction for the Formation of Labile Bonds between Group 13 and Group 15 Atoms
Thomas, Florian,Schulz, Stephan,Mansikkamaeki, Heidi,Nieger, Martin
, p. 5641 - 5644 (2003)
The heterocycles [{Me2AIE(SiMe3)2} x] (E = P-Bi) are powerful metathesis reagents in the presence of 4-dimethyl-aminopyridine (dmap), thus allowing the synthesis of previously unknown Group 13/15 compounds. Reactions with [Me3M-dmap] (M = In, TI) proceed with E(SiMe3)2 transfer to form the corresponding heterocycles [{Me2InBi-(SiMe3) 2}3] and [{Me2TIE(SiMe3) 2}2] (E = P, As), which were characterized by NMR and MS analysis, and by single-crystal X-ray diffraction.
