81206-47-5

Basic information

• Product Name: ethyl (Z)-2-(2-ethoxyethenyl)benzoate
• Synonyms: ethyl (Z)-2-(2-ethoxyethenyl)benzoate
• CAS NO: 81206-47-5
• Molecular Weight: 220.268
• Mol File: 81206-47-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl (Z)-2-(2-ethoxyethenyl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (Z)-2-(2-ethoxyethenyl)benzoate(81206-47-5)
• EPA Substance Registry System: ethyl (Z)-2-(2-ethoxyethenyl)benzoate(81206-47-5)

Safety Data

• Hazardous Substances Data: 81206-47-5(Hazardous Substances Data)

Upstream product

• 6091-64-1 2-bromobenzoic acid ethyl ester 
• 64724-29-4 tributyl-((Z)-2-ethoxy-vinyl)-stannane 
• 32763-41-0 tris((E)-2-ethoxyvinyl)borane 
• 1829-28-3 ethyl 2-iodobenzoate 

Relevant articles and documents

Condensed heteroaromatic ring systems. XVII. Palladium-catalyzed cross-coupling reaction of aryl bromides with (Z)-1-ethoxy-2-tributylstannylethene and its utilization for construction of condensed heteroaromatics

The palladium-catalyzed cross-coupling reaction of bromobenzenes or bromoheteroarenes such as pyridine, thiophene, indole with (Z)-1-ethoxy-2-tributylstannylethene gives good yields of the corresponding (Z)-1-ethoxy-2-(aryl and heteroaryl)ethenes. This method is effective for introducing an ethoxyethenyl group into an aromatic and heteroaromatic ring and is proved to have versatile utility for the construction of benzo[b]furan, indole, isocoumarin rings 2-bromophenol, 2-bromoaniline, and 2-bromobenzoate derivatives.