81236-83-1

Basic information

• Product Name: Cyclopropanecarboxaldehyde, 1-(trimethylsilyl)-
• CAS NO: 81236-83-1
• Molecular Formula: C7H14OSi
• Molecular Weight: 142.273
• Mol File: 81236-83-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Cyclopropanecarboxaldehyde, 1-(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanecarboxaldehyde, 1-(trimethylsilyl)-(81236-83-1)
• EPA Substance Registry System: Cyclopropanecarboxaldehyde, 1-(trimethylsilyl)-(81236-83-1)

Safety Data

• Hazardous Substances Data: 81236-83-1(Hazardous Substances Data)

Upstream product

• 18293-53-3 2-trimethylsilylacetonitrile 
• 31469-29-1 (1'-(trimethylsilyl)cyclopropyl)carboxylic acid 
• 81236-68-2 Trimethyl-(1-methylselanyl-cyclopropyl)-silane 
• 68-12-2 N,N-dimethyl-formamide 
• 91686-39-4 1-(Trimethylsilyl)cyclopropanenitrile 
• 91633-48-6 <1-(Trimethylsilyl)cyclopropyl>carbinol 
• 55287-89-3 2-(trimethylsilyl)prop-2-en-1-ol 

Downstream Products

• 83718-75-6 {1-[2,6-Dimethyl-cyclohex-2-en-(Z)-ylidenemethyl]-cyclopropyl}-trimethyl-silane 
• 91445-08-8 (Z)-1-<<1-(Trimethylsilyl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene 
• 91633-65-7 3-Ethoxy-5-methyl-6-methyl>cyclohex-2-enone 
• 91633-66-8 3-Ethoxy-5-methyl-6-<<1-(trimethylsilyl)cyclopropyl>methylene>cyclohex-2-enone 
• 91633-60-2 1--1-(trimethylsilyl)cyclopropane 
• 91444-99-4 (2-Methyl-1-phenylselanyl-cyclohexyl)-(1-trimethylsilanyl-cyclopropyl)-methanol 
• 91444-98-3 (1-Phenylselanyl-cyclohexyl)-(1-trimethylsilanyl-cyclopropyl)-methanol 
• 91445-01-1 (1-Phenylselanyl-cyclopentyl)-(1-trimethylsilanyl-cyclopropyl)-methanol 

Relevant articles and documents

Synthesis and reactivity of α-lithio α-trimethylsilyl cyclopropanes and related derivatives

α-lithio α-trimethylsilyl cyclopropanes have been prepared by two different routes. They have been tested as precursors of alkylidene cyclopropanes, cyclopropylidienes and α-silyl α-vinyl cyclopropanes.

Synthesizing Molecules with Linear Tricyclic 5/5/5 and 6/5/5 Skeletons via [5 + 2 + 1]/Ene Strategy

Report here is the development of a [5 + 2 + 1]/ene strategy for the synthesis of molecules with linear tricyclic 5/5/5 and 6/5/5 skeletons widely found in natural products. The first step of this strategy is applying a Rh-catalyzed [5 + 2 + 1] reaction o

SILICON IN ORGANIC SYNTHESIS. 16. A SHORT SYNTHESIS OF (+/-)-α-VETISPIRENE

α-Vetispirene, a prototypical spirobicyclic sesquiterpene, has been prepared in an efficient five-step reaction sequence beginning with α-trimethylsilyl cyclopropanecarboxaldehyde.A new desiliconative alkylation is featured.