81312-33-6

Basic information

• Product Name: Methyl 2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranoside
• Synonyms: Methyl 2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranoside
• CAS NO: 81312-33-6
• Molecular Weight: 406.315
• Mol File: 81312-33-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methyl 2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranoside(81312-33-6)
• EPA Substance Registry System: Methyl 2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranoside(81312-33-6)

Safety Data

• Hazardous Substances Data: 81312-33-6(Hazardous Substances Data)

Upstream product

• 56390-10-4 methyl 2,3,6-trideoxy-3-(trifluoroacetamido)-α-L-lyxo-hexopyranoside 
• 122-04-3 4-nitro-benzoyl chloride 

Downstream Products

• 132817-48-2 2,3,6-Trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-1-O-trimethylsilyl-α-L-lyxo-hexopyranose 
• 132814-67-6 1-O-tert-butyldimethylsilyl 4-O-p-nitrobenzoyl-2,3,6-trideoxy-3-trifluoroacetamido-β-L-lyxo-hexopyranoside 
• 81312-34-7 2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-L-lyxo-hexopyranose 
• 81312-35-8 2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-L-lyxo-hexopyranose 
• 76753-25-8 2,3,6-Trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-L-lyxo-hexopyranose 
• 81312-37-0 ethyl 2-(2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-L-lyxo-hexopyranosyl)acetate 

Relevant articles and documents

C-DAUNOSAMINYL DERIVATIVES BY THE WITTIG REACTION

C-Glycosylation of a 2-deoxypyranose has been achieved for the first time by conversion of 4-O-p-nitrobenzoyl-N-trifluoroacetyldaunosamine in a Wittig reaction into the corresponding derivative of ethyl 2-(daunosaminyl)acetate.The product was predominantly (54percent) in the desired α-L configuration (separated from the β-L anomer, 15percent) required for further elaboration of C-daunosaminyl derivatives.Conversion into the corresponding derivatives of 2-(α-L-daunosaminyl)acetaldehyde and 2-(α-L-daunosaminyl)ethanol was also achieved.