81336-59-6

Basic information

• Product Name: quinolin-6-yl benzoate
• Synonyms: quinolin-6-yl benzoate
• CAS NO: 81336-59-6
• Molecular Weight: 249.269
• Mol File: 81336-59-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: quinolin-6-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: quinolin-6-yl benzoate(81336-59-6)
• EPA Substance Registry System: quinolin-6-yl benzoate(81336-59-6)

Safety Data

• Hazardous Substances Data: 81336-59-6(Hazardous Substances Data)

Upstream product

• 1271739-73-1 O-(6-quinolinyl) O-phenyl thiocarbonate 
• 123-30-8 4-amino-phenol 
• 580-16-5 6-hydroxyquinoline 
• 98-88-4 benzoyl chloride 
• 65-85-0 benzoic acid 

Downstream Products

• 580-16-5 6-hydroxyquinoline 
• 65-85-0 benzoic acid 
• 93-99-2 benzoic acid phenyl ester 

Relevant articles and documents

Highly chemoselective deoxygenation of N-heterocyclic: N -oxides under transition metal-free conditions

Because their site-selective C-H functionalizations are now considered one of the most useful tools for synthesizing various N-heterocyclic compounds, the highly chemoselective deoxygenation of densely functionalized N-heterocyclic N-oxides has received much attention from the synthetic chemistry community. Here, we provide a protocol for the highly chemoselective deoxygenation of various functionalized N-oxides under visible light-mediated photoredox conditions with Na2-eosin Y as an organophotocatalyst. Mechanistic studies imply that the excited state of the organophotocatalyst is reductively quenched by Hantzsch esters. This operationally simple technique tolerates a wide range of functional groups and allows high-yield, multigram-scale deoxygenation. This journal is

DIRECT CONVERSION OF PHENOLS INTO AMIDES AND ESTERS OF BENZOIC ACID

A method is provided for the preparation of an aromatic carboxylic acid aryl ester or an N-aryl aromatic carboxamide. The method comprises contacting an O,O-diaryl thiocarbonate or an O-aryl-N-aryl thiocarbamate with a reactant that regioselectively reacts with sulfur, which contact causes an O-neophyl rearrangement, thereby forming either the aromatic carboxylic acid aryl ester or the N-aryl aromatic carboxamide, respectively.