81345-04-2Relevant articles and documents
Total synthesis of marine oxylipin bacillariolides I-III
Miyaoka, Hiroaki,Tamura, Masahide,Yamada, Yasuji
, p. 8083 - 8094 (2007/10/03)
Marine oxylipin bacillariolides I-III were synthesized from (R)-malic acid, using diastereoselective one-pot formation of the chiral cyclopentane derivative from the anion of allyl phenyl sulfone and chiral epoxymesylate as the key reaction. (C) 2000 Elsevier Science Ltd.
FOUR NEW C15 ACETYLENIC POLYENES OF BIOGENETIC SIGNIFICANCE FROM THE RED ALGA LAURENCIA OKAMURAI: STRUCTURES AND SYNTHESIS
Kigoshi, Hideo,Shizuri, Yoshikazu,Niwa, Haruki,Yamada, Kiyoyuki
, p. 3781 - 3788 (2007/10/02)
From the red alga Laurencia okamurai four new C15 acetylenic polyenes, laurencenyne 6, neolaurencenyne 8, and trans-neolaurencenyne 9 have been isolated and their structures were elucidated by chemical and spectral means.Synthesis of these four compounds has been made to confirm their structural and stereochemical assigments.Biogenesis of laurencenyne 6 and trans-laurencenyne 8 was discussed.
